Preparation and Storage of the Interhalogen Iodine Monobromide IBr
In this video I prepare the interhalogen compound iodine monobromide from equimolar amounts of elemental bromine (10 grams) and elemental iodine (15.88 grams). IBr is an interesting compound since the iodine bears a partial positive charge and the bromine a partial negative carge. IBr is used to cleave carbon-metal bonds to produce organic iodides and metal bromides. It is also used to convert alkenes into vicinal bromoiodides, effect the electrophilic cyclization of homoallylic carbonates, and alpha-bromination of steroidal aldehydes and ketones. IBr has also been used for brominating phenol and aryl ether derivatives. (Information taken from the Encyclopedia of Reagents for Organic Sythesis).
In this video I prepare niobium pentabromide and the oxytribromide from niobium and bromine in an atmosphere of CO2.
Donate via Paypal: https://www.paypal.com/paypalme/PoorMansChemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
YouTube: https://www.youtube.com/poormanschemist
BitChute: https://www.bitchute.com/poormanschemist/
Minds: https://www.minds.com/poormanschemist/
Sellers of Hard to Find Chems
BackyardScience2000 Bonanza Store:
https://www.bonanza.com/booths/Backyardscience2000
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/torste_88?_trksid=p2047675.l2559
BackyardScience2000 Mercari Store:
https://www.mercari.com/u/242693481/
BackyardScience2000 Poshmark Store:
https://poshmark.com/closet/bys2k
In this video I prepare an arsenic compound that I could find very little information about but that is synthetic useful for making other arsenic compounds according to the literature I can find. All I have to go on is what atomistry has to say about it (link below).
Donate via Paypal: https://www.paypal.com/paypalme/PoorMansChemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www bitchute com/poormanschemist/
YouTube: https://www youtube com/poormanschemist
Minds: https://www minds com/poormanschemist/
Atomistry Page on Potassium Arsenites: http://arsenic.atomistry.com/potassium_arsenites.html
Sellers of Hard to Find Chems
BackyardScience2000 Bonanza Store:
https://www bonanza com/booths/Backyardscience2000
BackyardScience2000 Ebay Store:
https://www ebay com/usr/torste_88?_trksid=p2047675 l2559
BackyardScience2000 Mercari Store:
https://www mercari com/u/242693481/
BackyardScience2000 Poshmark Store:
https://poshmark com/closet/bys2k
Demonstrating the synthesis of azeotropic hydrobromic acid from elemental bromine, elemental sulfur, and ice water. The synthesis protocol is taken from prepchem.com and can be found at:
http://www.prepchem.com/synthesis-of-hydrobromic-acid/ "6) Preparation of hydrobromic acid from sulfur and bromine"
The reactions involved in the synthesis are:
1) 2S + Br2 --- S2Br2
2) S2Br2 + 5Br2 + 8H2O --- 12HBr + 2H2SO4
Donate via PayPal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via CashApp: $poormanschemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www.bitchute.com/poormanschemist/
YouTube: https://www.youtube.com/poormanschemist
Sellers of Hard to Find Chems
Backyardscience2000 Email (ask for a full product list)
backyardscience2000@gmail.com
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/backyard-science-2000
Bacyardscience2000 CashApp:
$backyardscience2000
In this video I prepare CsReO4 from rhenium metal. The bulk piece of rhenium is converted to precipitated rhenium powder which is then dissolved in a minimal amount of nitric acid to form perrhenic acid. This is then converted to ammonium perrhenate by addition of aqueous ammonia. Addition of a slight stoichiometric excess of cesium chloride creates cesium perrhenate.
Donate via PayPal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via CashApp: $poormanschemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www.bitchute.com/poormanschemist/
YouTube: https://www.youtube.com/poormanschemist
Sellers of Hard to Find Chems
Backyardscience2000 Email (ask for a full product list)
backyardscience2000@gmail.com
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/backyard-science-2000
Bacyardscience2000 CashApp:
$backyardscience2000
I replicate Nile Red's synthesis of elemental bromine from aqueous alkali bromide, 16% HCl, and trichloroisocyanuric acid a.k.a. trichloro-s-triazinetrione obtained from 3" pool chlorinating tablets. You can see his video that I took the synthesis protocol from by clicking the link at the bottom of the description. A typical run of this synthesis requires the materials listed below. Since I did my run from bromide that I had recovered and recycled from previous reactions my measurements were different. You can find the step by step protocol for this synthesis on my website at: http://www.poormanschemist.com/PMC_Grimoire/PMC_Grimoire.html#bromine
Donate via PayPal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via CashApp: $poormanschemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www.bitchute.com/poormanschemist/
YouTube: https://www.youtube.com/poormanschemist
Sellers of Hard to Find Chems
Backyardscience2000 Email (ask for a full product list)
backyardscience2000@gmail.com
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/backyard-science-2000
Bacyardscience2000 CashApp:
$backyardscience2000
I react chunks of iron covered with sodium potassium cyanide (a byproduct of the sodium potassium cyanide synthesis) with ~6M HCl to produce very fine particles of Prussian Blue. The acid reacts with the cyanide ion to produce HCN in solution. The acid also dissolves the iron producing ferrous chloride. Oxygen in solution reacts with some of that producing ferric chloride. Once Fe(II), Fe(III), and CN- are all present Prussian Blue forms and precipitates out in fine particles. This is allowed to settle, the liquid is decanted, and the solid is rinsed with water. This process is repeated several times until all of the ferric chloride solution has been removed.
Donate via Paypal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Donate via CashApp: $poormanschemist
Discord Invite: https://discord.gg/pyKBwuZNqT
Website: www.poormanschemist.com
Email: poormanschemist@gmail.com
BitChute: https://www.bitchute.com/poormanschemist/
Odysee: https://odysee.com/@poormanschemist:9
Preparation of thallium(I) nitrate from thallium sulfate by metathesis with barium sulfate followed by filtration and crystallization. Got some excellent timelapse video of the crystallization process; some of my best in my opinion.
Paypal: https://www.paypal.com/paypalme/PoorMansChemist1
CashApp: $poormanschemist
Patreon: https://www.patreon.com/PoorMansChemist84
Subscribe Star: https://www.subscribestar.com/poormanschemist
Email: poormanschemist@gmail.com
BitChute: https://www.bitchute.com/poormanschemist/
Odysee: https://odysee.com/@poormanschemist:9
In this video I make up a few uranyl compounds as described on atomistry. We start with making thallium uranyl carbonate followed by uranyl hypophosphite which I then turn into uranyl metaphosphate.
Donate via PayPal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via CashApp: $poormanschemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www.bitchute.com/poormanschemist/
YouTube: https://www.youtube.com/poormanschemist
Sellers of Hard to Find Chems
Backyardscience2000 Email (ask for a full product list)
backyardscience2000@gmail.com
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/backyard-science-2000
Bacyardscience2000 CashApp:
$backyardscience2000
In this video I make up a mixture of phosphorus selenides as I attempt to make phosphorus triselenide. As it was I ended up with three selenides of phosphorus. Next I made up a solution of potassium selenocyanate from selenium and potassium ferrocyanide. Then I precipitate out lead selenocyanate, mercuric selenocyanate, and copper selenocyanate.
Phosphorus Monoselenide = http://selenium.atomistry.com/phosphorus_monoselenide.html
Phosphorus Triselenide = http://selenium.atomistry.com/phosphorus_triselenide.html
Tetraphosphorus Triselenide = http://selenium.atomistry.com/tetraphosphorus_triselenide.html
Phosphorus Pentaselenide = http://selenium.atomistry.com/phosphorus_pentaselenide.html
Potassium Selenocyanate = http://selenium.atomistry.com/potassium_selenocyanate.html
Caesium Triselenocyanate = http://selenium.atomistry.com/caesium_triselenocyanate.html
Copper Selenocyanate = http://selenium.atomistry.com/copper_selenocyanate.html
Lead Selenocyanate = http://selenium.atomistry.com/lead_selenocyanate.html
Mercurous Selenocyanate = http://selenium.atomistry.com/mercurous_selenocyanate.html
Mercuric Selenocyanate = http://selenium.atomistry.com/mercuric_selenocyanate.html
Donate via PayPal: https://www.paypal.com/paypalme/PoorMansChemist1
Donate via CashApp: $poormanschemist
Donate via Subscribe Star: https://www.subscribestar.com/poormanschemist
Website: www.poormanschemist.com
Discord Server Invite: https://discord.gg/THQTew8
Email: poormanschemist@gmail.com
Odysee: https://open.lbry.com/@poormanschemist:9
BitChute: https://www.bitchute.com/poormanschemist/
YouTube: https://www.youtube.com/poormanschemist
Sellers of Hard to Find Chems
Backyardscience2000 Email (ask for a full product list)
backyardscience2000@gmail.com
BackyardScience2000 Ebay Store:
https://www.ebay.com/usr/backyard-science-2000
Bacyardscience2000 CashApp:
$backyardscience2000