Fortunately this is a very mild process and doesn't need exotic conditions like ultraviolet light or high temperatures.
We reflux together 7.2g of potassium iodide, 19g of sodium cyanide, 50g of p-chlorobenzyl chloride and 250mL of dry acetone for at least one full day.
What happens is the iodide replaces the benzylic chloride on the p-chlorobenzyl chloride in a reaction known as the Finkelstein reaction. This highly reactive p-chlorobenzyl iodide now reacts with sodium cyanide to form p-chlorobenzyl cyanide, or p-chlorophenyl acetonitrile.
How to make TCPO or bis(2,4,6-trichlorophenyl) oxalate, used in glow stick reactions.
WARNING: This procedure should only be performed by, or under the direct supervision of, an experienced chemist. Please refer to the material safety data sheets of all chemicals for their hazards. Synthesis must be performed in a fumehood.
The exact same process is used in glow sticks. This is NOT mountain dew. Mountain dew cannot glow like this, it does not have the crucial TCPO chemical or any chemical like that.
The reaction will glow in the dark for several minutes if you use ethyl acetate as the solvent. It will glow for several hours if you use diethyl phthalate as the solvent.
Thanks for watching!
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https://www.youtube.com/watch?v=ViJknvEEEOA
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I go back to sticking my hand into liquid nitrogen but remain uninjured due to the Leidenfrost effect.
The Leidenfrost effect is the formation of a gas barrier between a hot surface and a boiling liquid if the temperature difference is great enough. This gas barrier greatly slows the heat transfer between the two and allows the liquid to last longer and consequently the hot surface to remain hot longer. This effect can be seen in a frying pan as it's being heated. At first the water quickly boils as it's dropped in but at a hot enough temperature the Leidenfrost effect takes over and makes the water skate around the surface lasting a very long time.
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https://www.youtube.com/watch?v=wV7g8L633Sg
We show the chemistry of photography using silver chloride that we make ourselves from table salt and silver nitrate.
Silver chloride has the interesting property that it reacts to light. This photosensitive chemical will decompose into dark silver powder and chlorine.
To make it, just mix one gram of silver nitrate made in our previous video ( http://www.youtube.com/watch?v=d6hPgGV_qAg ) and half a gram of salt in separate quantities of water. Then mix the two solutions with shaking, this forms silver chloride. Then let it stand for five minutes. This will cause the silver chloride to settle to the bottom. After five minutes pour off the extra liquid. Spread out the silver in a layer onto a piece of paper. Let it dry in darkness as you don't want the light to expose it before you're ready. Once it is dry, place a stencil or template of something you want "photographed" over the silver chloride. You might want to weigh it down with a piece of glass.
When you're ready, shine a strong light onto it for ten minutes or so. The silver chloride will darken in the areas that are exposed to light. Remove the glass and template and you will have a negative photo of what you placed over it.
The image won't keep forever, eventually the whole thing will darken.
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https://www.youtube.com/watch?v=8e0-AbwBDYM
Just sticking together and then pulling apart two pieces of duct tape will cause them to produce a blue line of light in an effect called triboluminescence.
Special thanks to Ashi58 for letting me use his footage, his channel can be seen here: http://www.youtube.com/user/ashi58
What's happening is that the action of pulling apart the glue causes charge separation in the two strips. The charges then attempt to recombine and collide with nearby molecules (of tape, glue, or air) exciting them and releasing light.
Interestingly, in a vacuum there is no air to slow down the charges so they collide at full energy and release x-rays. This serves as the basis for the sticky-tape x-ray machine published in the journal Nature.
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https://www.youtube.com/watch?v=54R6q2_-4Yo
Update: Sept 3rd:
Thanks for all your help, you did what i couldn't do, got youtube to listen. The problems seem to be fixed now. We'll see if they persist in subsequent uploads. But for now i am hopeful.
Thanks again for helping me out. There is no need to send further feedback to youtube UNLESS you are one of my subs that haven't been receiving notifications or sub-feeds for other videos and not just my sulfuric acid video. If that's the case, if you've had other problems, by all means send feedback detailing your issues. Be sure to include links to videos that haven't shown up in your feed.
I'll leave this video up so we have evidence in case future errors occur. But you can skip it for now.
Thanks again.
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https://www.youtube.com/watch?v=serRqpdYo3k
In this video, we explore the process of making potassium permanganate, a valuable oxidant with a striking purple color. Starting with 43g of manganese dioxide, often obtained from greensand filter media, and 25g of potassium chlorate, the chemicals are thoroughly mixed. A can made of iron is chosen as the reaction vessel due to its resistance to the highly corrosive mixture.
All reagents are mixed long with 40mL of water and 60g of potassium hydroxide. The can is placed in a furnace and heated to 400 degrees Celsius for several hours. This step involves the oxidation of manganese dioxide to potassium manganate by potassium chlorate, with potassium hydroxide providing essential potassium ions and alkaline conditions.
Once cooled and soaked in water, the solid chunks of potassium manganate are retrieved. To convert potassium manganate into potassium permanganate, chlorine gas is used. A chlorine generator comprising 45g of trichloroisocyanuric acid in 100mL water and 75mL of 30% hydrochloric acid is employed to produce chlorine gas, which is then introduced into the potassium manganate flask. The reaction results in potassium permanganate with potassium chloride as a byproduct.
Once the reaction is complete, the mixture is vacuum-filtered and then chilled to separate potassium permanganate from potassium chloride and hypochlorite. The potassium permanganate crystals are beautiful black needles.
The final yield is approximately 30.7g or 39%, adjusted to 52% considering the purity of the manganese dioxide used. Both crystallizations of potassium permanganate are found to be 99% pure with a 1% margin of error, confirmed through titration.
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https://www.youtube.com/watch?v=62jzXwn3-G4
We show how to make hydrochloric acid from sodium bisulfate and table salt.
The synthesis is rather simple, we generate hydrogen chloride gas by mixing together 140g of sodium bisulfate and 60g of sodium chloride salt and then heating. 20mL of water can be added to lower the temperature required but this is optional. Hydrogen chloride gas will be produced. This gas is lead into distilled water to produce hydrochloric acid. Be careful though, hydrogen chloride is so soluble that the water will pull itself into the tube trying to absorb it. In the video i use an elaborate back-flow prevention system to prevent loss of the product.
Sodium bisulfate is available as a pH lowering chemical. 30mL of sulfuric acid may be used as a replacement if you have it. Although if you had that, you probably don't need hydrochloric acid.
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https://www.youtube.com/watch?v=YGjd7xxTuZw
Using sodium hydroxide (drain cleaner) we dissolve glass.
Glass is nearly invulnerable to chemicals and thus why it's the preferred material for chemical containers and reaction vessels. But when exposed to molten sodium hydroxide even glass will dissolve.
To perform the reaction a steel container is used as it's resistant to the sodium hydroxide.
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https://www.youtube.com/watch?v=nmktRTHL1NA
In this video we the thermal decomposition of copper to directly produce nitric acid without using any other acid.
Normally to make nitric acid you react a nitrate salt with a strong acid like sulfuric acid. But what if we wanted to make it without any acids at all? Copper nitrate has the interesting property that if it's heated it will decompose into nitrogen dioxide and oxygen, two components needed for nitric acid. Best of all copper nitrate itself can be made with domestically available that don't require acid either.
First calcium ammonium nitrate is boiled with calcium hydroxide to produce pure calcium nitrate. This is done only to remove ammonia and not necessary if calcium nitrate can be obtained directly. Calcium ammonium nitrate is a fertilizer. The resulting calcium nitrate is reacted with copper sulfate which is available as a root killer. The resulting copper nitrate solution and calcium sulfate are filtered and the copper nitrate is boiled to remove most of the water until it starts to change color to green/blue.
The copper nitrate is then hooked up a distillation apparatus and heated until it decomposes. The nitrogen dioxide gas produced is lead into water to dissolve. The nitric acid produced is then purified by distillation. Yield is between 60%-80%
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https://www.youtube.com/watch?v=hmB5x0LYfSE